Green Arrow and Black Canary
Hawkeye and Black Widow are hailed as this generation's quintessential superhero couple, but, for the record, their relationship in the comics was typically on-again, off-again. For a more solid pairing of archer and femme fatale, look no further than Green Arrow and Black Canary. Since the late '60s—and before the New 52—these two had been steadfast lovers, not once allowing their careers as urban vigilantes come between them. In fact, their wedding was chronicled in 2007's Green Arrow and Black Canary Wedding Special #1. And in standard hero fashion, wedding bells chimed and chaos ensued.