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The Rate Law
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Introduction to Stoichiometry

 
 

Rate Law Problems

 
Problem 1.1:

C2H5O- + CH3Br→C2H5OCH3 + Br-    

The above reaction has the following rate law:

rate = k[C2H5O-]a[CH3Br]b    

If [C2H5O-] is tripled while [CH3Br] is constant, the rate of the reaction also triples. If [CH3Br] is doubled while [C2H5O-] is constant, the rate of the reaction is also doubled. What are the values of a and b? What is the overall reaction order?
 
Problem 1.2: Which one of the following steps is rate-limiting?
 
Problem 1.3: Sketch the reaction coordinate vs. energy for the reaction given in the previous problem.
 
 
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